也不知道新的EN 71-3 标准到底进行到什么程度了,翻遍了网络,只找到了最新的Draft的目录,大家将就看看吧(能看到新版的草案中已经给出了有机锡和铬形态分析的具体方法,包括具体要测试的有机锡的种类,等等)。十分期待有人放出全文! !$XHQLqF2
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Foreword
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Introduction V`a+Hi<P\
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1 Scope T.?k>Ak
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2 Normative references r)l`
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3 Terms and definitions Wpm9`K
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4 Requirements nmE5]Pcg
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4.1 Categories of toy materials
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4.1.1 Category I: Dry, brittle, dust-like or pliable material 9/;{>RL=
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4.1.2 Category II: Liquid or adhesive material #S?c ;3-
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4.1.3 Category III: material scraped =HPu{K$
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4.1.4 Categories of different toy materials `@\^m_!}
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4.2 Specific Requirements Ld~4nc$H8
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5 Short Description Qg{WMlyOP
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6 Reagents and Equipment TPqvp|~2
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1.6 Reagents %OFj
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6.2 Device mc~`
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7 Sampling and Sample Preparation +|M{I= 8
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7.1 Selection of samples for analysis `L;OY 4
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7.2 Preparation of standards z=[l.Af_
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7.3 Sample Preparation 4u7Cm
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7.3.1 Category I: Dry, brittle, smooth or powdery materials and Category II: Liquid or sticky materials
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7.3.2 Category III: material scraped eS*
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4.7 migration procedures )Kxs@F
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7.4.1 General pb~Ps#"Zg
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7.4.2 Category I: Dry, brittle, smooth or powdery materials and Category II: Liquid or sticky materials )J{.Cx<E
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8 Analysis Method ]!n*V/g
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8.1 General "Nk`RsW
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8.2 Chromium (VI) (speciation) 8 /:X&
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3.8 Organotin UXcH";*9b
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9 Calculation of results [|c@
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9.1 Standard Elements \4]zNV ~x
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9.1.1 Calibration Curves URmAI8fq*M
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9.1.2 Calculation of the concentration x):k#cu[L
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9.1.3 Evaluation +*r**(-Dm
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9.2 Chromium (III) and chromium (VI) #sm_.?P
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9.2.1 Calibration Curves NP<F==,
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9.2.2 Calculation of the concentration CL@h!h554_
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9.2.3 Evaluation dbq{a
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9.3.1 Calibration Curves Jr>S/]"
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9.3.2 Calculation of the migration of individual organotin compounds ng&EGM
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9.3.3 Calculation of the migration of organotin R$;&O.
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9.3.4 Evaluation e9_O/i N
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10 Test report WKIiJ{@L
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Annex A (informative) Significant technical changes between this European Standard and the previous version 0G\myv
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Annex B (informative) Results of laboratory proficiency testing - migration of elements (May 2012) OUk5c$M(
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Annex C (normative) Requirements for Sieve F4<
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Annex D (informative) Preparation and analysis of the sample )zt4'b\)v
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Annex E (informative) Preparation of standards k Q(y^t W
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E.1 ICP-MS >@Vr'kg+V
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E.1.1 stock solution (M1) Tn-]0hWkP
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E.1.2 Diluted stock solution (M2) Z2jb>%
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E.1.3 Work Solutions Fh$&puF2
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E.2 ICP-OES wR$8drn]Rq
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E.2.1 stock solution (M1) P$Ru NF
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E.2.2 Work Solutions i]?xM2(N
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Annex F (informative) Analysis Method Pv.@Y30
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F.1 ICP-parameter s9Z2EjQV
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F.2 method for speciation of chromium hiHp@"l<
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F.2.1 Scope G)7sXEe
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F.2.2 Summary sc60:IxgI
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F.2.3 reagents 2_X0Og8s[
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F.2.5 Method <!^Z|E
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F.2.6 reporting -;}Wm[
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F.2.7 Example for LC-ICP-MS conditions ?9+;[X
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F.3 procedures for organotin zYgLGwi{
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F.3.1 Scope #Z : r
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F.3.2 terms
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F.3.3 Summary F~EriO
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F.3.4 reagents ;\h'A(
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F.3.5 test equipment %Xn)$Ti~<
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F.3.6 process 0/c4%+
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F.3.7 Example for the gas chromatography conditions }+z}vb
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Annex G (informative) Rationale %lujme
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G.1 skin contact (scope) cB|](gWS~
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G.2 organotin (F.3.7.2) L;Nm"[`
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Annex H (informative) Additional information on inspection of certain elements y8\44WKW
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Annex ZA (informative) Relationship between this European Standard and the Essential Requirements of EU Directive 2009/48/EC (If (created in due time)) }z}oVc
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